Nearly every 256-bit number is a valid ECDSA private key. Specifically, any 256-bit number from 0x1 to 0xFFFF FFFF FFFF FFFF FFFF FFFF FFFF FFFE BAAE DCE6 AF48 A03B BFD2 5E8C D036 4140 is a valid private key.
The range of valid private keys is governed by the secp256k1 ECDSA standard used by Bitcoin.