dic_value VARCHAR(MAX)
Вы не сможете сделать ограничение уникальности на это поле. Создайте вычисляемое поле, например, хеш и ограничивайте его.
CREATE TABLE [dbo].[Dic](
[ID] [int] IDENTITY(1,1) NOT NULL,
[Value] [varchar](max) NOT NULL,
[ValueUnique] AS (hashbytes('MD5',[Value])),
CONSTRAINT [PK_Dic] PRIMARY KEY CLUSTERED
(
[ID] ASC
)WITH (PAD_INDEX = OFF, STATISTICS_NORECOMPUTE = OFF, IGNORE_DUP_KEY = OFF,
ALLOW_ROW_LOCKS = ON, ALLOW_PAGE_LOCKS = ON) ON [PRIMARY]
) ON [PRIMARY] TEXTIMAGE_ON [PRIMARY]
GO
CREATE UNIQUE NONCLUSTERED INDEX [IX_Dic] ON [dbo].[Dic]
(
[ValueUnique] ASC
)WITH (PAD_INDEX = OFF, STATISTICS_NORECOMPUTE = OFF, SORT_IN_TEMPDB = OFF, IGNORE_DUP_KEY = OFF,
DROP_EXISTING = OFF, ONLINE = OFF, ALLOW_ROW_LOCKS = ON, ALLOW_PAGE_LOCKS = ON) ON [PRIMARY]
GO