PATH
уберите путь к старому и вставьте к новому. H:\My Documents\PyCharm>py
Python 3.5.2 (v3.5.2:4def2a2901a5, Jun 25 2016, 22:18:55) [MSC v.1900 64 bit (AMD64)] on win32
Type "help", "copyright", "credits" or "license" for more information.
>>> quit()
H:\My Documents\PyCharm>py -2
Python 2.7.12 (v2.7.12:d33e0cf91556, Jun 27 2016, 15:24:40) [MSC v.1500 64 bit (AMD64)] on win32
Type "help", "copyright", "credits" or "license" for more information.
>>> quit()