Попробовал так, но не работает.
<Window.Resources>
<ControlTemplate TargetType="Button" x:Key="btTemp">
<Border x:Name="ButtonBorders" Background="{TemplateBinding Background}" BorderThickness="0" CornerRadius="5" Height="{TemplateBinding Height}" Width="{TemplateBinding Width}">
<ContentControl Foreground="{TemplateBinding Foreground}" Content="{TemplateBinding Content}" VerticalAlignment="Center" HorizontalAlignment="Center" FontSize="{TemplateBinding FontSize}" FontFamily="{TemplateBinding FontFamily}"/>
</Border>
<ControlTemplate.Triggers>
<Trigger Property="IsMouseOver" Value="True">
<Setter TargetName="ButtonBorders" Property="Background" Value="LightSeaGreen"/>
<Setter Property="Control.Foreground" Value="DarkOliveGreen"/>
<Setter Property="Cursor" Value="Hand"/>
</Trigger>
</ControlTemplate.Triggers>
</ControlTemplate>
</Window.Resources>
<Grid Background="#FF6A6A6A">
<Button Template="{StaticResource btTemp}" Content="Button" HorizontalAlignment="Left" Margin="268,214,0,0" VerticalAlignment="Top" Width="174" Height="67" FontSize="22" FontFamily="Segoe UI Black" Background="#FF785A5A" Foreground="White"/>
</Grid>