Котик Антон

Потому что в ответе от сервера у вас:
Content-Type:text/html; charset=windows-1251

Где-то в коде (CMS) похоже задана windows-1251.

RewriteRule ^catalog/(.+)$ http://%{HTTP_HOST}/$1 [R=301,L]

1. Настройки OpenServer > Домены
2. Управление доменами > Ручное управление
3. Указываете имя домена и папку, где лежит index.php
4. Жмёте [Добавить]

В htaccess забыли "access plus 1 week". И все перечисленное - директивы модуля mod_expires, а не mod_headers.

Я использую такой вариант:

<IfModule mod_expires.c>
    ExpiresActive on

    ExpiresDefault "access plus 1 month"

    ExpiresByType text/cache-manifest "access plus 0 seconds"

    <FilesMatch \.(html|xhtml|xml|shtml|phtml|php|txt)$>
        ExpiresDefault "access plus 0 seconds"
    </FilesMatch>
    ExpiresByType text/html                 "access plus 0 seconds"
    ExpiresByType text/xml                  "access plus 0 seconds"
    ExpiresByType application/xml           "access plus 0 seconds"
    ExpiresByType application/json          "access plus 0 seconds"

    ExpiresByType application/rss+xml       "access plus 1 hour"
    ExpiresByType application/atom+xml      "access plus 1 hour"

    <FilesMatch \.(ico)$>
        ExpiresDefault "access plus 1 week"
    </FilesMatch>
    ExpiresByType image/x-icon "access plus 1 week"

    <FilesMatch \.(gif|png|jpg|jpeg|ogg|mp4|mkv|flv|swf|wmv|asf|asx|wma|wax|wmx|wm)$>
        ExpiresDefault "access plus 1 year"
    </FilesMatch>
    ExpiresByType image/gif                 "access plus 1 month"
    ExpiresByType image/png                 "access plus 1 month"
    ExpiresByType image/jpeg                "access plus 1 month"
    ExpiresByType video/ogg                 "access plus 1 month"
    ExpiresByType audio/ogg                 "access plus 1 month"
    ExpiresByType video/mp4                 "access plus 1 month"
    ExpiresByType video/webm                "access plus 1 month"
    ExpiresByType text/x-component          "access plus 1 month"

    <FilesMatch \.(eot|ttf|otf|svg|woff)$>
        ExpiresDefault "access plus 1 year"
    </FilesMatch>
    ExpiresByType application/x-font-ttf    "access plus 1 month"
    ExpiresByType font/opentype             "access plus 1 month"
    ExpiresByType application/x-font-woff   "access plus 1 month"
    ExpiresByType image/svg+xml             "access plus 1 month"

    <FilesMatch \.(css|js)$>
        ExpiresDefault "access plus 1 year"
    </FilesMatch>
    ExpiresByType text/css                  "access plus 1 year"
    ExpiresByType application/javascript    "access plus 1 year"
</IfModule>

httpd.apache.org/docs/2.2/mod/mod_dir.html#directo...

Добавьте в начало .htaccess:
DirectorySlash Off

RewriteCond %{HTTP_USER_AGENT} (android|bb\d+|meego).+mobile|avantgo|bada\/|blackberry|blazer|compal|elaine|fennec|hiptop|iemobile|ip(hone|od)|iris|kindle|lge\ |maemo|midp|mmp|netfront|opera\ m(ob|in)i|palm(\ os)?|phone|p(ixi|re)\/|plucker|pocket|psp|series(4|6)0|symbian|treo|up\.(browser|link)|vodafone|wap|windows\ (ce|phone)|xda|xiino [NC]

Чтобы охватить все мобильные браузеры, используйте:

RewriteCond %{HTTP_USER_AGENT} (android|bb\d+|meego).+mobile|avantgo|bada\/|blackberry|blazer|compal|elaine|fennec|hiptop|iemobile|ip(hone|od)|iris|kindle|lge\ |maemo|midp|mmp|mobile.+firefox|netfront|opera\ m(ob|in)i|palm(\ os)?|phone|p(ixi|re)\/|plucker|pocket|psp|series(4|6)0|symbian|treo|up\.(browser|link)|vodafone|wap|windows\ ce|xda|xiino [NC,OR]
RewriteCond %{HTTP_USER_AGENT} ^(1207|6310|6590|3gso|4thp|50[1-6]i|770s|802s|a\ wa|abac|ac(er|oo|s\-)|ai(ko|rn)|al(av|ca|co)|amoi|an(ex|ny|yw)|aptu|ar(ch|go)|as(te|us)|attw|au(di|\-m|r\ |s\ )|avan|be(ck|ll|nq)|bi(lb|rd)|bl(ac|az)|br(e|v)w|bumb|bw\-(n|u)|c55\/|capi|ccwa|cdm\-|cell|chtm|cldc|cmd\-|co(mp|nd)|craw|da(it|ll|ng)|dbte|dc\-s|devi|dica|dmob|do(c|p)o|ds(12|\-d)|el(49|ai)|em(l2|ul)|er(ic|k0)|esl8|ez([4-7]0|os|wa|ze)|fetc|fly(\-|_)|g1\ u|g560|gene|gf\-5|g\-mo|go(\.w|od)|gr(ad|un)|haie|hcit|hd\-(m|p|t)|hei\-|hi(pt|ta)|hp(\ i|ip)|hs\-c|ht(c(\-|\ |_|a|g|p|s|t)|tp)|hu(aw|tc)|i\-(20|go|ma)|i230|iac(\ |\-|\/)|ibro|idea|ig01|ikom|im1k|inno|ipaq|iris|ja(t|v)a|jbro|jemu|jigs|kddi|keji|kgt(\ |\/)|klon|kpt\ |kwc\-|kyo(c|k)|le(no|xi)|lg(\ g|\/(k|l|u)|50|54|\-[a-w])|libw|lynx|m1\-w|m3ga|m50\/|ma(te|ui|xo)|mc(01|21|ca)|m\-cr|me(rc|ri)|mi(o8|oa|ts)|mmef|mo(01|02|bi|de|do|t(\-|\ |o|v)|zz)|mt(50|p1|v\ )|mwbp|mywa|n10[0-2]|n20[2-3]|n30(0|2)|n50(0|2|5)|n7(0(0|1)|10)|ne((c|m)\-|on|tf|wf|wg|wt)|nok(6|i)|nzph|o2im|op(ti|wv)|oran|owg1|p800|pan(a|d|t)|pdxg|pg(13|\-([1-8]|c))|phil|pire|pl(ay|uc)|pn\-2|po(ck|rt|se)|prox|psio|pt\-g|qa\-a|qc(07|12|21|32|60|\-[2-7]|i\-)|qtek|r380|r600|raks|rim9|ro(ve|zo)|s55\/|sa(ge|ma|mm|ms|ny|va)|sc(01|h\-|oo|p\-)|sdk\/|se(c(\-|0|1)|47|mc|nd|ri)|sgh\-|shar|sie(\-|m)|sk\-0|sl(45|id)|sm(al|ar|b3|it|t5)|so(ft|ny)|sp(01|h\-|v\-|v\ )|sy(01|mb)|t2(18|50)|t6(00|10|18)|ta(gt|lk)|tcl\-|tdg\-|tel(i|m)|tim\-|t\-mo|to(pl|sh)|ts(70|m\-|m3|m5)|tx\-9|up(\.b|g1|si)|utst|v400|v750|veri|vi(rg|te)|vk(40|5[0-3]|\-v)|vm40|voda|vulc|vx(52|53|60|61|70|80|81|83|85|98)|w3c(\-|\ )|webc|whit|wi(g\ |nc|nw)|wmlb|wonu|x700|yas\-|your|zeto|zte\-) [NC]

Источник: detectmobilebrowsers.com